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The jawline
vimeo.com/35732667

I don't do a lot of portraits, but next time I do, this tutorial by Peter Hurley on accentuating the jawline will have increased my chances of getting the shot I'm after. The video perhaps oversells the point a little bit, but you can't dispute the results. 15 minutes well spent, watching this. Hope you enjoy!

(I found this video through a recommendation by David Malki of Wondermark fame.)